how to fill dictionary in c#

var students = new Dictionary<int, StudentName>()
{
    { 111, new StudentName {FirstName="Sachin", LastName="Karnik", ID=211}},
    { 112, new StudentName {FirstName="Dina", LastName="Salimzianova", ID=317}},
    { 113, new StudentName {FirstName="Andy", LastName="Ruth", ID=198}}
};

private readonly Dictionary<string, XlFileFormat> FILE_TYPE_DICT
        = new Dictionary<string, XlFileFormat>
        {
            {"csv", XlFileFormat.xlCSV},
            {"html", XlFileFormat.xlHtml}
        };